Bis{μ-(E)-methyl 4-[(2-carbamothioylhydrazinylidene)methyl]benzoate-κ2 S:S}bis[iodido(triphenylphosphane-κP)copper(I)]
نویسندگان
چکیده
The title complex, [Cu(2)I(2)(C(10)H(11)N(3)O(2)S)(2)(C(18)H(15)P)(2)], is a centrosymmetric sulfur-bridged dimer of Cu(I) with PPh(3) and iodine. The Cu(I) atom shows a distorted tetra-hedral geometry, with bite angles ranging from 98.61 (2) to 120.16 (3)°. The intra-molecular Cu⋯Cu distance is 2.8228 (12) Å. The thio-semicarbazone ligand is coordinated only through the S atom. In the crystal, the complex mol-ecules are linked via inter-molecular N-H⋯O hydrogen bonds, resulting in a hydrogen-bonded chain along the b axis.
منابع مشابه
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011